Experimental growth of åkermanite reaction rims between wollastonite and monticellite: evidence for volume diffusion control     

Bastian Joachim  Emmanuel Gardés  Rainer Abart  Wilhelm Heinrich 《Contributions to Mineralogy and Petrology》2011,161(3):389-399

Growth rates of monomineralic, polycrystalline åkermanite (Ca₂MgSi₂O₇) rims produced by solid-state reactions between monticellite (CaMgSiO₄) and wollastonite (CaSiO₃) single crystals were determined at 0.5 GPa dry argon pressure, 1,000–1,200°C and 5 min to 60 h, using an internally heated pressure vessel. Inert Pt-markers, initially placed at the monticellite–wollastonite interface, indicate symmetrical growth into both directions. This and mass balance considerations demonstrate that rim growth is controlled by transport of MgO. At 1,200°C and run durations between 5 min and 60 h, rim growth follows a parabolic rate law with rim widths ranging from 0.4 to 16.3 μm indicating diffusion-controlled rim growth. The effective bulk diffusion coefficient \( D_{\text{eff,MgO}}^{\text{Ak}} \) is calculated to 10^?15.8±0.1 m² s^?1. Between 1,000°C and 1,200°C, the effective bulk diffusion coefficient follows an Arrhenius law with E _a = 204 ± 18 kJ/mol and D ₀ = 10^?8.6±1.6 m² s^?1. Åkermanite grains display a palisade texture with elongation perpendicular to the reaction interface. At 1,200°C, average grain widths measured normal to elongation, increase with the square root of time and range from 0.4 to 5.4 μm leading to a successive decrease in the grain boundary area fraction, which, however, does not affect \( D_{\text{eff,MgO}}^{\text{Ak}} \) to a detectible extent. This implies that grain boundary diffusion only accounts for a minor fraction of the overall chemical mass transfer, and rim growth is essentially controlled by volume diffusion. This is corroborated by the agreement between our estimates of the effective MgO bulk diffusion coefficient and experimentally determined volume diffusion data for Mg and O in åkermanite from the literature. There is sharp contrast to the MgO–SiO₂ binary system, where grain boundary diffusion controls rim growth.  相似文献   

From Predictive Mapping of Mineral Prospectivity to Quantitative Estimation of Number of Undiscovered Prospects     

Emmanuel J. M. Carranza 《Resource Geology》2011,61(1):30-51

This paper proposes that the spatial pattern of known prospects of the deposit‐type sought is the key to link predictive mapping of mineral prospectivity (PMMP) and quantitative mineral resource assessment (QMRA). This proposition is demonstrated by PMMP for hydrothermal Au‐Cu deposits (HACD) and by estimating the number of undiscovered prospects for HACD in Catanduanes Island (Philippines). The results of analyses of the spatial pattern of known prospects of HACD and their spatial associations with geological features are consistent with existing knowledge of geological controls on hydrothermal Au‐Cu mineralization in the island and elsewhere, and are used to define spatial recognition criteria of regional‐scale prospectivity for HACD. Integration of layers of evidence representing the spatial recognition criteria of prospectivity via application of data‐driven evidential belief functions results in a map of prospective areas occupying 20% of the island with fitting‐ and prediction‐rates of 76% and 70%, respectively. The predictive map of prospective areas and a proxy measure for degrees of exploration based on the spatial pattern of known prospects of HACD were used in one‐level prediction of undiscovered mineral endowment, which yielded estimates of 79 to 112 undiscovered prospects of HACD. Application of radial‐density fractal analysis of the spatial pattern of known prospects of HACD results in an estimate of 113 undiscovered prospects of HACD. Thus, the results of the study support the proposition that PMMP can be a part of QMRA if the spatial pattern of discovered prospects of the deposit‐type sought is considered in both PMMP and QMRA.  相似文献   

Formation of the Dongmozhazhua Pb–Zn Deposit in the Thrust‐Fold Setting of the Tibetan Plateau,China: Evidence from Fluid Inclusion and Stable Isotope Data     

YingChao LIU  ZengQian HOU  ZhuSen YANG  ShiHong TIAN  TianNan YANG  YuCai SONG  HongRui ZHANG  Emmanuel John M. CARRANZA 《Resource Geology》2011,61(4):384-406

The Dongmozhazhua deposit, the largest Pb–Zn deposit in south Qinghai, China, is stratabound, carbonate‐hosted and associated with epigenetic dolomitization and silicification of Lower–Middle Permian—Upper Triassic limestones in the hanging walls of a Cenozoic thrust fault system. The mineralization is localized in a Cenozoic thrust‐folded belt along the northeastern edge of the Tibetan plateau, which was formed due to the India–Asia plate collision during the early Tertiary. The deposit comprises 16 orebodies with variable thicknesses (1.5–26.3 m) and lengths (160–1820 m). The ores occur as dissemination, vein, and breccia cement. The main sulfide assemblage is sphalerite + galena + pyrite + marcasite ± chalcopyrite ± tetrahedrite, and gangue minerals consist mainly of calcite, dolomite, barite, and quartz. Samples of pre‐ to post‐ore stages calcite yielded δ¹³C and δ¹⁸O values that are, respectively, similar to and lower than those yielded by the host limestones, suggesting that the calcite formed from fluids derived from carbonate dissolution. Fluid inclusions in calcite and sphalerite in the polymetallic sulfidization stage mostly comprise liquid and gas phases at room temperature, with moderate homogenization temperatures (100–140°C) and high salinities (21–28 wt% NaCl eq.). Micro‐thermometric fluid inclusion data point to polysaline brines as ore‐forming fluids. The δD and δ¹⁸O values of ore fluids, cation compositions of fluid inclusions, and geological information suggest two main possible fluid sources, namely basinal brines and evaporated seawater. The fluid inclusion data and regional geology suggest that basinal brines derived from Tertiary basins located southeast of the Dongmozhazhua deposit migrated along deep detachment zones of the regional thrust system, leached substantial base metals from country rocks, and finally ascended along thrust faults at Dongmozhazhua. There, the base‐metal‐rich basinal brines mixed with bacterially‐reduced H₂S‐bearing fluids derived from evaporated seawater preserved in the Permo–Triassic carbonate strata. The mixing of the two fluids resulted in Pb–Zn mineralization. The Dongmozhazhua Pb–Zn deposit has many characteristics that are similar to MVT Pb–Zn deposits worldwide.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111000405   总被引：1，自引：0，他引：1  

Jean de la Paix Mupenzi  Lanhai Li  Jiwen Ge  Achal Varenyam  Gabriel Habiyaremye  Nzayisenga Theoneste  Kamanzi Emmanuel 《地学前缘(英文版)》2011,2(4):599-607

This study has focused on the processes of soil degradation and chemical element concentration in tea-growing regions of Rwanda, Africa. Soil degradation accelerated by erosion is caused not only by topography but also by human activities. This soil degradation involves both the physical loss and reduction in the amount of topsoil associated with nutrient decline. Soil samples were collected from eleven tropical zones in Rwanda and from variable depth within each collecting site. Of these, Samples from three locations in each zone were analyzed in the laboratory, with the result that the pH of all soil samples is shown to be less than 5 (pH < 5) with a general average of 4.4. The elements such as iron (Fe), copper (Cu), manganese (Mn), and zinc (Zn) are present in high concentration levels. In contrast calcium (Ca) and sodium (Na) are present at low-level concentrations and carbon (C) was found in minimal concentrations. In addition, elements derived from fertilizers, such as nitrogen (N), phosphorous (P), and potassium (K) which is also from minerals such as feldspar, are also present in low-level concentrations. The results indicate that the soil in certain Rwandan tea plantations is acidic and that this level of pH may help explain, in addition to natural factors, the deficiency of some elements such as Ca, Mg, P and N. The use of chemical fertilizers, land use system and the location of fields relative to household plots are also considered to help explain why tea plantation soils are typically degraded.  相似文献   

Marine renewable energy: The ecological implications of altering the hydrodynamics of the marine environment     

Mark A. Shields  David K. WoolfEric P.M. Grist  Sandy A. KerrA.C. Jackson  Robert E. HarrisMichael C. Bell  Robert BeharieAndrew Want  Emmanuel OsalusiStuart W. Gibb  Jonathan Side 《Ocean & Coastal Management》2011,54(1):2-9

Many countries now recognise the need for mitigation of climate change induced by human activities and have incorporated renewable energy resources within their energy policy. There are extensive resources of renewable energy within the marine environment and increasing interest in extracting energy from locations with either large tidal range, rapid flow with and without wave interaction, or large wave resources. However, the ecological implications of altering the hydrodynamics of the marine environment are poorly understood. Ecological data for areas targeted for marine renewable developments are often limited, not least because of the considerable challenges to sampling in high energy environments. In order to predict the scale and nature of ecological implications there is a need for greater understanding of the distribution and extent of the renewable energy resource and in turn, of how marine renewable energy installations (MREIs) may alter energy in the environment. Regional ecological implications of a MREI need to be considered against the greater and global ecological threat of climate change. Finally, it is recommended that the identification of species and biotopes susceptible to the removal of hydrokinetic energy could be a suitable strategy for understanding how a MREI may alter flow conditions.  相似文献   

Mineralogical and Geochemical Constraints on the Genesis of the Carbonate‐Hosted Jebel Ghozlane Pb–Zn Deposit (Nappe Zone,Northern Tunisia)     

Nejib Jemmali  Fouad Souissi  Emmanuel John M. Carranza  Torsten W. Vennemann 《Resource Geology》2013,63(1):27-41

The Pb–Zn deposit at Jebel Ghozlane, in the Nappe zone (northern Tunisia), is hosted by Triassic dolostones and Eocene limestones and is located along faults and a thrust‐sheet boundary. The sulfide mineralization of the deposit consists mainly of galena and sphalerite and occurs as vein, stockwork, breccia, dissemination and replacement ores. Three hydrothermal stages are involved in the formation of the ores: stage I is dominated by celestite‐barite, hydrothermal dolomite DII, colloform sphalerite, and galena I; stage II consist of galena II; and stage III contains calcite. Galena in the deposit yielded average ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 18.705, 15.667 and 38.734, respectively, suggesting a single upper crustal source reservoir for metals. Trace element data indicate the presence of Zn‐ and As‐free galena and As‐rich galena (with 0.2–0.5% As). Sphalerite contains 0.4% As, 0.7–0.9% Cd and 0.1–1.5% Fe. Microthermometric analysis of fluid inclusions in celestite shows that the deposit formed from fluids composed of heterogeneous mixtures of saline (19.5 ± 1 wt% NaCl eq.) aqueous solutions sourced from basinal brines, and gaseous CO₂‐rich phases bearing low amounts of CH₄, N₂ and/or H₂S, at temperatures of 172 ± 5°C.  相似文献   

Trace element geochemistry of CR chondrite metal     

Emmanuel Jacquet  Marine Paulhiac‐Pison  Olivier Alard  Anton T. Kearsley  Matthieu Gounelle 《Meteoritics & planetary science》2013,48(10):1981-1999

We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h^?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.  相似文献   

On the mathematical stability of stratified flow models with local turbulence closure schemes     

Eric Deleersnijder  Emmanuel Hanert  Hans Burchard  Henk A. Dijkstra 《Ocean Dynamics》2008,58(3-4):237-246

Occasionally, numerical simulations using local turbulence closure schemes to estimate vertical turbulent fluxes exhibit small-scale oscillations in space, causing the eddy coefficients to vary over several orders of magnitude on short distances. Theoretical developments suggest that these spurious oscillations are essentially due to the way the eddy coefficients depend on the vertical gradient of the model’s variables. An instability criterion is derived based on the assumptions that the artefacts under study are due to the development of small-amplitude, small time- and space-scale perturbations of a smooth solution. The relevance of this criterion is demonstrated by applying it to a series a closure schemes, ranging from the Pacanowski–Philander formulas to the Mellor–Yamada level 2.5 model.  相似文献   

Turbulent kinetic energy budget in a gravel-bed channel flow     

Emmanuel Mignot  Eric Barthélemy  David Hurther 《Acta Geophysica》2008,56(3):601-613

The present experimental investigation focuses on the characteristics of near bed turbulence in a fully rough, uniform open-channel flow over a gravel-type bed. Due to bed topography small scale heterogeneity, the flow is not uniform locally in the near bed region and a double averaging methodology is applied over a length scale much larger than the gravel size. The double-averaged Turbulent Kinetic Energy (TKE) budget derived in the context of the present flow over a gravel bed differs from the TKE budget written for flow over a vegetation canopy. The non-constant shape of the roughness function measured in our gravel bed leads to an additional bed-induced production term which is null for vertical roughness elements, such as simplified vegetation elements. The experimental estimation of the terms of the TKE budget reveals that the maximum turbulent activity takes place away from the reference plane, near the roughness crests. However, within the interface sublayer the work of the bed induced velocity fluctuations against the Reynolds stress is of the same magnitude as the main turbulence production term. Consequently, the characteristics of the TKE budget have similarities with uniform flows over canopies and strongly differ from uniform flows over smooth and transitionally rough flows over sedimentlike beds.  相似文献   

Application of Mineral Exploration Models and GIS to Generate Mineral Potential Maps as Input for Optimum Land-Use Planning in the Philippines   总被引：4，自引：0，他引：4  

Carranza  Emmanuel John M.  Mangaoang  Jerrysal C.  Hale  Martin 《Natural Resources Research》1999,8(2):165-173

The inherent problems of classifying or inventorying potential mineral resources (as opposed to known mineral resources) pose specific challenges. In this paper, the application of a conceptual mineral exploration model and GIS to generate mineral potential maps as input to land-use policy decision-making is illustrated. We implement the criteria provided by a conceptual exploration model for nickeliferous-laterites by using a GIS to classify the nickeliferous-laterite potential of an area in the northeastern part of the Philippines. The spatial data inputs to the GIS are geological map data, topographic map data, and stream sediment point data. Processing of these data yields derivative maps, which are used as indicators of nickeliferous-laterite potential. The indicator maps then are integrated to furnish a nickeliferous-laterite potential map. This map is compared with present land-use classification and policy in the area. The results indicate high potential for nickeliferous-laterite occurrence in the area, but the zones of potential are in places where mineral resources development is prohibited. The prohibition was imposed before the nickeliferous-laterite potential was assessed by this study. Mineral potential classification therefore is a critical input to land-use policy-making so that prospective land is not alienated from future mineral resource development.  相似文献